Grease and line a 23cm round cake tin and set aside. Preheat oven to 160 degrees celsius (fan-forced) or 320 degrees fahrenheit.
Measure the cocoa powder, flour, bi-carbonate soda, baking powder, caster sugar and salt into the Thermomix bowl and sift for 5 seconds, Speed 8. Set aside in a separate bowl.
Place the the vegetable oil, eggs, buttermilk, finely grated zest and orange juice into the Thermomix bowl and mix for 15 seconds, Speed 3 until well combined.
With the blades on Speed 2, slowly add the dry ingredients to the wet ingredients and mix until smooth and combined.
Pour mixture into the prepared tin and bake for 30-35 minutes or until a skewer inserted into the middle comes out with a few crumbs on it. Set aside to cool before turning out onto a wire rack.
To make the ganache, place the dark chocolate into a clean and dry Thermomix bowl and grate for 10 seconds, Speed 8. Add the cream and heat for 2 minutes, 50 degrees, Speed 3.
Allow the ganache to chill in the fridge until slightly thickened (if needed) before spreading over the top of the cooled cake.